Stellite 21

Stellite 21 is a cobalt-chromium-molybdenum alloy optimized for impact, galling, and corrosion resistance. It is ideal for CNC-machined components requiring toughness, thermal stability, and sliding wear performance in critical service environments.

Introduction to Stellite 21

Stellite 21 is a wrought cobalt-based alloy known for its exceptional toughness, corrosion resistance, and high-temperature mechanical stability. Unlike other Stellite grades prioritizing hardness and abrasion resistance, Stellite 21 is engineered for applications requiring wear resistance, superior impact, and thermal shock performance. Its balanced composition of cobalt, chromium, nickel, and molybdenum provides excellent metallurgical stability and resistance to galling, making it suitable for sliding contact and mechanical shock.

Stellite 21 is often produced via forging or casting, then precision-finished using advanced CNC machining techniques. It is commonly used in aerospace, nuclear, petrochemical, and medical industries for components like valve seats, engine sleeves, joint implants, and turbine hardware—particularly where dimensional stability and low-friction metal-to-metal contact are essential.


Chemical, Physical, and Mechanical Properties of Stellite 21

Stellite 21 (UNS R30021 / AMS 5385 / ISO 5832-3) is a corrosion- and wear-resistant cobalt-chromium-molybdenum alloy with enhanced impact strength and thermal fatigue resistance. It is available in wrought, cast, and powder metallurgy forms.

Chemical Composition (Typical)

Element

Composition Range (wt.%)

Key Role

Cobalt (Co)

Balance (≥60.0)

Base matrix for corrosion, toughness, and thermal strength

Chromium (Cr)

26.0–30.0

Enhances oxidation resistance and forms a passive protective layer

Molybdenum (Mo)

5.0–6.0

Increases pitting and crevice corrosion resistance

Nickel (Ni)

2.0–4.0

Improves toughness and weldability

Carbon (C)

0.20–0.30

Forms carbides for wear resistance while maintaining ductility

Iron (Fe)

≤3.0

Residual element

Silicon (Si)

≤1.0

Improves surface finish and flow during casting

Manganese (Mn)

≤1.0

Refines grain structure and improves hot workability


Physical Properties

Property

Value (Typical)

Test Standard/Condition

Density

8.33 g/cm³

ASTM B311

Melting Range

1385–1435°C

ASTM E1268

Thermal Conductivity

14.0 W/m·K at 100°C

ASTM E1225

Electrical Resistivity

0.98 µΩ·m at 20°C

ASTM B193

Thermal Expansion

13.4 µm/m·°C (20–400°C)

ASTM E228

Specific Heat Capacity

430 J/kg·K at 20°C

ASTM E1269

Elastic Modulus

210 GPa at 20°C

ASTM E111


Mechanical Properties (Wrought or HIP + Heat Treated)

Property

Value (Typical)

Test Standard

Hardness

30–35 HRC (annealed) / 35–42 HRC (aged)

ASTM E18

Tensile Strength

900–1100 MPa

ASTM E8/E8M

Yield Strength (0.2%)

400–600 MPa

ASTM E8/E8M

Elongation

8–15%

ASTM E8/E8M

Impact Toughness

≥80 J (Charpy V-notch at RT)

ASTM E23

Galling Resistance

Excellent

ASTM G98


Key Characteristics of Stellite 21

  • High Toughness and Crack Resistance: Superior to other Stellite grades due to lower carbon content, enabling resistance to thermal fatigue, impact loading, and mechanical shocks.

  • Corrosion Resistance in Chloride and Acidic Media: Excellent pitting and crevice corrosion resistance due to molybdenum and chromium synergy.

  • Good Galling Resistance: Performs well in metal-to-metal contact applications under pressure without lubrication.

  • Dimensional Stability at High Temperature: Operates reliably up to 850°C in cyclic thermal environments, with minimal distortion or degradation.


CNC Machining Challenges and Solutions for Stellite 21

Machining Challenges

Moderate Carbide Content

  • While less abrasive than Stellite 6 or 12, tool wear remains an issue due to distributed carbides and the alloy’s toughness.

Low Thermal Conductivity

  • Causes localized heating and risk of work hardening, especially in finishing operations or during long tool engagements.

Springback and Tool Deflection

  • High modulus and strength can lead to tool chatter and dimensional inaccuracies during roughing and profile cuts.


Optimized Machining Strategies

Tool Selection

Parameter

Recommendation

Rationale

Tool Material

PVD-coated carbide (K20–K30) or CBN for finishing

Balances wear resistance and toughness

Coating

TiSiN or AlCrN (3–5 µm)

Reduces tool temperature and friction

Geometry

Neutral to slightly negative rake, honed cutting edge (0.03 mm)

Enhances edge integrity and surface finish

Cutting Parameters (ISO 3685 Compliant)

Operation

Speed (m/min)

Feed (mm/rev)

Depth of Cut (mm)

Coolant Pressure (bar)

Roughing

12–18

0.15–0.25

1.5–2.5

100–120

Finishing

20–28

0.05–0.10

0.5–1.0

120–150


Surface Treatment for Machined Stellite 21 Parts

Hot Isostatic Pressing (HIP)

HIP improves fatigue life and removes internal porosity, especially important for cast or 3D-printed parts under dynamic loading.

Heat Treatment

Heat Treatment stabilizes grain structure and enhances hardness while relieving residual stress from machining.

Superalloy Welding

Superalloy Welding using matching filler (Stellite 21 rod) ensures high joint integrity without compromising corrosion or wear resistance.

Thermal Barrier Coating (TBC)

TBC Coating extends part life in applications exposed to combustion or hot gases above 800°C.

Electrical Discharge Machining (EDM)

EDM achieves complex geometries with Ra <0.5 µm while avoiding mechanical stress during finishing.

Deep Hole Drilling

Deep Hole Drilling ensures accuracy in wear-resistant bores, seal cavities, and lubrication channels.

Material Testing and Analysis

Material Testing includes tensile testing, hardness verification, metallography, and NDT (ultrasonic, dye penetrant, X-ray).


Industry Applications of Stellite 21 Components

Aerospace & Power Generation

  • Valve guides, bushings, and high-load sliding wear components for turbine engines and hot section assemblies.

Nuclear & Petrochemical

  • Reactor valve seats, pump shafts, and control hardware resistant to high-pressure corrosion and radiation exposure.

Medical & Orthopedic Devices

  • Hip and knee joint components due to excellent biocompatibility and mechanical durability under dynamic loading.

General Industry

  • Tools, wear pads, and bearing sleeves used in reciprocating or oscillating wear conditions under pressure.


FAQs

  1. What machining strategies help minimize tool wear and deformation in Stellite 21 components?

  2. How does Stellite 21 perform in corrosive and high-impact operating environments?

  3. Can Stellite 21 be used in medical applications requiring biocompatibility?

  4. What heat treatment and post-processing steps enhance Stellite 21's performance after CNC machining?

  5. What dimensional tolerances and surface finishes can be achieved with Stellite 21 using EDM?

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