Stellite SF12

Stellite SF12 is a high-performance cobalt-based alloy designed for CNC-machined parts operating in wear-intensive, high-temperature environments. It offers a superior combination of weldability, carbide hardness, and corrosion resistance for control valves, turbine parts, and energy sector machinery.

Introduction to Stellite SF12

Stellite SF12 is a cobalt-based alloy developed for extreme wear, heat, and corrosion resistance, particularly in applications involving metal-to-metal contact, thermal cycling, and fluid erosion. It combines a moderate carbon level with elevated tungsten and chromium content, forming a tough, wear-resistant matrix reinforced with hard carbides.

Compared to conventional Stellite alloys like Stellite 6 or Stellite 12, SF12 is formulated for enhanced weldability and improved toughness without compromising hardness. It is widely applied through welding overlays, casting, or powder metallurgy and is frequently precision-finished via CNC machining for use in aerospace, energy, petrochemical, and industrial valve systems.


Chemical, Physical, and Mechanical Properties of Stellite SF12

Stellite SF12 (also referred to as AWS ERCoCr-A analog) is a wear-resistant cobalt-chromium-tungsten alloy designed for elevated temperature and corrosive environments with frequent sliding or erosive contact.

Chemical Composition (Typical)

Element

Composition Range (wt.%)

Key Role

Cobalt (Co)

Balance (≥50.0)

Provides thermal and chemical stability

Chromium (Cr)

27.0–30.0

Enhances oxidation and corrosion resistance

Tungsten (W)

3.5–5.0

Increases hardness through carbide formation

Carbon (C)

1.2–1.5

Enables wear resistance via carbide distribution

Nickel (Ni)

≤3.0

Improves toughness and thermal fatigue resistance

Iron (Fe)

≤3.0

Residual element

Silicon (Si)

≤1.2

Enhances casting flow and surface finish

Manganese (Mn)

≤1.0

Supports deoxidation and solidification control


Physical Properties

Property

Value (Typical)

Test Standard/Condition

Density

8.55 g/cm³

ASTM B311

Melting Range

1315–1395°C

ASTM E1268

Thermal Conductivity

13.2 W/m·K at 100°C

ASTM E1225

Electrical Resistivity

0.95 µΩ·m at 20°C

ASTM B193

Thermal Expansion

13.0 µm/m·°C (20–400°C)

ASTM E228

Specific Heat Capacity

425 J/kg·K at 20°C

ASTM E1269

Elastic Modulus

210 GPa at 20°C

ASTM E111


Mechanical Properties (As-Cast or Weld Overlay Condition)

Property

Value (Typical)

Test Standard

Hardness

45–52 HRC

ASTM E18

Tensile Strength

1050–1200 MPa

ASTM E8/E8M

Yield Strength (0.2%)

580–680 MPa

ASTM E8/E8M

Elongation

2.0–3.5%

ASTM E8/E8M

Galling Resistance

Excellent

ASTM G98

Operating Temperature

Up to 1050°C

N/A


Key Characteristics of Stellite SF12

  • Optimized Wear Resistance with Improved Weldability: SF12 achieves high hardness from carbide dispersion while maintaining thermal ductility and lower residual stress compared to Stellite 12.

  • Thermal Stability under Fatigue Conditions: Retains hardness and mechanical integrity after repeated thermal cycling in service environments such as valves and combustion chambers.

  • Superior Metal-to-Metal Sliding Resistance: Exhibits low friction and no adhesive wear under boundary lubrication or dry contact scenarios.

  • Corrosion Resistance in Acidic and Alkaline Media: Chromium-enriched matrix resists oxidation, corrosion, and steam erosion across a wide pH spectrum.


CNC Machining Challenges and Solutions for Stellite SF12

Machining Challenges

High Hardness and Carbide Density

  • Carbides formed during solidification significantly reduce tool life, particularly under aggressive roughing or interrupted cuts.

Low Thermal Conductivity

  • Poor heat dissipation leads to local thermal overload and accelerated wear of uncoated carbide tools.

Work Hardening

  • Strain-induced surface hardening occurs rapidly, resulting in tool deflection, vibration, and reduced finish accuracy.


Optimized Machining Strategies

Tool Selection

Parameter

Recommendation

Rationale

Tool Material

K40 micrograin carbide or CBN/PCBN inserts

Withstands abrasion from carbides

Coating

TiAlN or AlCrN (3–5 µm PVD)

Improves heat resistance and lubricity

Geometry

Neutral rake with 0.03–0.05 mm edge hone

Enhances edge durability and reduces chipping

Cutting Parameters (ISO 3685 Compliant)

Operation

Speed (m/min)

Feed (mm/rev)

Depth of Cut (mm)

Coolant Pressure (bar)

Roughing

10–14

0.20–0.25

1.5–2.5

100–120

Finishing

16–22

0.05–0.10

0.3–1.0

120–150


Surface Treatment for Machined Stellite SF12 Parts

Hot Isostatic Pressing (HIP)

HIP densifies internal structure, improving fatigue resistance and eliminating microvoids in cast or additively manufactured components.

Heat Treatment

Heat Treatment stabilizes carbide distribution and relieves residual stress post-machining.

Superalloy Welding

Superalloy Welding maintains mechanical integrity and chemical resistance in high-wear assembly joints.

Thermal Barrier Coating (TBC)

TBC Coating insulates exposed parts from flame or exhaust stream temperatures exceeding 950°C.

Electrical Discharge Machining (EDM)

EDM enables high-precision machining of SF12 overlays or hard-faced features.

Deep Hole Drilling

Deep Hole Drilling suits critical oil/steam flow channels with L/D > 20:1 and high roundness requirements.

Material Testing and Analysis

Material Testing includes carbide analysis, XRD phase verification, Rockwell hardness mapping, and ultrasonic defect detection.


Industry Applications of Stellite SF12 Components

Control Valves and Regulators

  • Seats stems, and cones operate under cavitation, high-velocity erosion, and thermal shock.

Aerospace Combustion Systems

  • Turbine shields, wear pads, and vane edges exposed to oxidizing gas flow and abrasive particulates.

Chemical and Steam Processing

  • Pump sleeves, impellers, and backplates in low-pH or high-saline media under rotating wear.

Oil & Gas Field Equipment

  • Downhole tools, valve internals, and drill bits resist impact, sand erosion, and chemical exposure.


FAQs

  1. What are the best cutting tools and parameters for machining high-hardness Stellite SF12?

  2. How does Stellite SF12 compare to Stellite 12 and Stellite 6 regarding weldability and toughness?

  3. Can Stellite SF12 components be finished using EDM or deep-hole drilling for complex geometries?

  4. What post-processing heat treatments enhance the performance and dimensional stability of SF12 parts?

  5. What industries typically require CNC machining of Stellite SF12 over traditional stainless or Inconel?

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